Ions in charge

Charge inversion and DNA condensation by multivalent ions Charge inversion and DNA condensation by multivalent ions

Koen BESTEMAN natuurkunding ingenieur geboren te Den Haag.

Charge states of ions, and mechanisms of charge ordering transitions.

To gain insight into the mechanism of charge ordering transitions, which conventionally are pictured as a disproportionation of an ion M as 2M(n+)→M((n+1)+) + M((n-1)+), we (1) review and reconsider the charge state (or oxidation number) picture itself, (2) introduce new results for the putative charge ordering compound AgNiO2 and the dual charge state insulator AgO, and (3) analyze the cationi...

Mass and Charge Measurements on Heavy Ions

The relationship between mass and charge has been a crucial topic in mass spectrometry (MS) because the mass itself is typically evaluated based on the m/z ratio. Despite the fact that this measurement is indirect, a precise mass can be obtained from the m/z value with a high m/z resolution up to 105 for samples in the low mass and low charge region under 10,000 Da and 20 e, respectively. Howev...

Cations in charge: magnesium ions in RNA folding and catalysis.

Polarization and charge transfer in the hydration of chloride ions.

A theoretical study of the structural and electronic properties of the chloride ion and water molecules in the first hydration shell is presented. The calculations are performed on an ensemble of configurations obtained from molecular dynamics simulations of a single chloride ion in bulk water. The simulations utilize the polarizable AMOEBA force field for trajectory generation and MP2-level ca...